I think the only ones i consider are "hot" are Vanessa from The little Mermaid, Malificent from Sleeping beauty and suprisingly Queen Narissa (animated)
But this is only compared to the other female villains
I think Maleficent from Sleeping Beauty, Mirage from Aladdin: The Animated Series, Demona from Gargoyles, Queen Grimhilde/The Evil Queen from Snow White and the Seven Dwarves, Queen Narissa from Enchanted, Queen La from The Legend of Tarzan and Shego from Kim Possible are hot, I can't decide who I think is hotter.
The Choice of the Male Disney Villains That I Like, I think is Handsome?, Either Captain James Hook, Jafar, Hades or Dr. Facilier, But I'll go with Captain James Hook, Because He is Hilarious, Elegant, Charismatic and Suave British Pirate Captain.
For me it's scar he's so smart such a genius so very elegant and he's a sexy beast and the gorgeous black hair and it's even styled (for some reason) and I just love green eyes and that sassy attitude turns me on
But the eyebrows.. PERFECT